Polymerisation

A polymer is a substance made up of many repeating units (called monomer units). Polymers are usually distinguished by a high molar mass (formula weight), often ranging into thousands or millions of grams per formula unit.

Polymerization is the process by which monomers (smaller chemical units) are combined to form a polymer. Polymerization is a poly-reaction of a monomer compound which molecule contains double bondings or rings The poly-reaction can occur under the following conditions:
The polymerization can be triggered by the following factors

  • Initiator (reaction partner)
  • Heat
  • Light
  • Radiation

Some unsaturated compounds with one or more double bonds are able to polymerise.

  • Vinyl compounds
  • Vinylidene compounds
  • Acrylic compounds
  • Carbonyl compounds
  • Styrene
  • Ethylene Oxide; Propylene Oxide
  • Ethylene, Propylene, Isobutylene, Butadiene and Isoprene

Definitions
homo-polymerization   Only one monomer is involved in the poli-reaction
co-polymerization          Two different monomers are involved in the poli-reaction
polimeric…….                  The product produced by the poli-reaction


Example

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Polyethylene polimerization reaction
Polyethylene polymerization reaction

Ethylene (C2H4) is a highly flammable gaseous molecule with a formula weight (molar mass) of 32 grams per mol. When polymerized using a catalyst, it forms an insoluble solid comprised of straight chains of CH2 units called Polyethylene. Polyethylene is a widely used commodity plastic.